Remoción de Mercurio (II) en solución acuosa usando residuo industrial de yuca (Manihot esculenta)

Autores/as

DOI:

https://doi.org/10.15665/rp.v17i2.1951

Palabras clave:

Adsorción, Hg (II), Metales pesados, Residuo Industrial, Yuca

Resumen

Se estudió la remoción de mercurio (II) en solución acuosa usando residuo industrial de yuca teniendo en cuenta variables como el pH y la concentración inicial del metal. El material adsorbente fue pretratado y caracterizado. Se determinó que la cinética de adsorción se ajusta a un modelo de primer orden y que el tiempo para el equilibrio de remoción es de dos horas. La capacidad máxima de remoción que se obtuvo fue de 0.03 mmol/g a una concentración inicial de mercurio (II) de 400 mg/L y a un pH de 6. Adicionalmente, se obtuvo que la adsorción de este metal a pH de 4.75 y 6 se ajusta de manera adecuada al modelo de adsorción de Langmuir.

Biografía del autor/a

Alberto Ricardo Albis Arrieta, Universidad del Atlántico

Profesor Asociado

Sergio Andrés Arzuza Orellano, Universidad del Atlántico

Ingeniero Químico

Adriana Margarita Mosquera PAlacio, Universidad del Atlántico

Ingeniera Química

Citas

A. Abdolali, W. Guo, H. H. Ngo, S.-S. Chen, N. C. Nguyen, and K. L. Tung, "Typical lignocellulosic wastes and by-products for biosorption process in water and wastewater treatment: a critical review", Bioresource technology, 160, 57-66, 2014.

E. Khoramzadeh, B. Nasernejad, and R. Halladj, "Mercury biosorption from aqueous solutions by sugarcane bagasse", Journal of the Taiwan Institute of Chemical Engineers, 44 (2), 266-269, 2013.

S. Basha, Z. Murthy, and B. Jha, "Sorption of Hg (II) onto Carica papaya: experimental studies and design of batch sorber", Chemical engineering journal, 147 (2-3), 226-234, 2009.

A. Esmaeili, B. Saremnia, and M. Kalantari, "Removal of mercury (II) from aqueous solutions by biosorption on the biomass of Sargassum glaucescens and Gracilaria corticata", Arabian Journal of Chemistry, 8 (4), 506-511, 2015.

S. Ricordel, S. Taha, I. Cisse, and G. Dorange, "Heavy metals removal by adsorption onto peanut husks carbon: characterization, kinetic study and modeling", Separation and purification technology, 24 (3), 389-401, 2001.

E. El-Shafey, "Removal of Zn (II) and Hg (II) from aqueous solution on a carbonaceous sorbent chemically prepared from rice husk", Journal of Hazardous Materials, 175 (1-3), 319-327, 2010.

N. Asasian, T. Kaghazchi, and M. Soleimani, "Elimination of mercury by adsorption onto activated carbon prepared from the biomass material", Journal of Industrial and Engineering Chemistry, 18 (1), 283-289, 2012.

S. H. Lee, C. H. Jung, H. Chung, M. Y. Lee, and J.-W. Yang, "Removal of heavy metals from aqueous solution by apple residues", Process Biochemistry, 33 (2), 205-211, 1998.

S.-A. Sajjadi, A. Mohammadzadeh, H. N. Tran, I. Anastopoulos, G. L. Dotto, Z. R. Lopičić, S. Sivamani, A. Rahmani-Sani, A. Ivanets, and A. Hosseini-Bandegharaei, "Efficient mercury removal from wastewater by pistachio wood wastes-derived activated carbon prepared by chemical activation using a novel activating agent", Journal of Environmental Management, 223, 1001-1009, 2018.

Z. Liu, W. Yang, W. Xu, and Y. Liu, "Removal of elemental mercury by bio-chars derived from seaweed impregnated with potassium iodine", Chemical engineering journal, 339, 468-478, 2018.

C. T. Tovar, E. R. Paternina, J. G. Mercado, and J. M. Bohorquez, "Evaluación de la biosorción con bagazo de palma africana para la eliminación de Pb (II) en solución", Prospectiva, 13 (1), 59-67, 2015.

R. Howeler, N. Lutaladio, and G. Thomas, "Save and grow: cassava, food and agriculture", Rome: Organization of the United Nations,2013.

M. P. Cereda and M. Takahashi, "Cassava wastes: their characterization and uses and treatment in Brazil", Cassava flour and starch: Progress in research and development, (271), 221-232, 1996.

A. Bhatnagar, M. Sillanpää, and A. Witek-Krowiak, "Agricultural waste peels as versatile biomass for water purification–a review", Chemical engineering journal, 270, 244-271, 2015.

M. Horsfall Jr and A. Abia, "Sorption of cadmium (II) and zinc (II) ions from aqueous solutions by cassava waste biomass (Manihot sculenta Cranz)", Water research, 37 (20), 4913-4923, 2003.

M. Pájaro and O. Romero, (2012) "Remoción de cromo (VI) en un medio acuoso mediante el uso de la cáscara de la yuca (Manihot esculenta)." Tesis de pregrado, Facultad de Ingeniería, Universidad del Atlántico, Barranquilla.

ICONTEC, "Productos Químicos Industriales. Carbón Activado. Métodos de Ensayo," vol. NTC 4467, ed. Bogotá: ICONTEC, 1998, p. 30.

M. Carrier, A. Loppinet-Serani, D. Denux, J.-M. Lasnier, F. Ham-Pichavant, F. Cansell, and C. Aymonier, "Thermogravimetric analysis as a new method to determine the lignocellulosic composition of biomass", Biomass and Bioenergy, 35 (1), 298-307, 2011.

I. De La Calle, N. Cabaleiro, V. Romero, I. Lavilla, and C. Bendicho, "Sample pretreatment strategies for total reflection X-ray fluorescence analysis: A tutorial review", Spectrochimica Acta Part B: Atomic Spectroscopy, 90, 23-54, 2013.

G. M. Gadd, "Biosorption: critical review of scientific rationale, environmental importance and significance for pollution treatment", Journal of Chemical Technology & Biotechnology: International Research in Process, Environmental & Clean Technology, 84 (1), 13-28, 2009.

O. Corredor Becerra, (2008) "Evaluación del potencial energético de la biomasa residual proveniente de cultivos energéticos." Ingeniero Químico, Universidad Industrial de Santander.

A. N. Kosasih, J. Febrianto, J. Sunarso, Y.-H. Ju, N. Indraswati, and S. Ismadji, "Sequestering of Cu (II) from aqueous solution using cassava peel (Manihot esculenta)", Journal of Hazardous Materials, 180 (1-3), 366-374, 2010.

P. Prinsen, "Composición química de diversos materiales lignocelulósicos de interés industrial y análisis estructural de sus ligninas",2010.

C. G. Rocha, D. A. M. Zaia, R. V. da Silva Alfaya, and A. A. da Silva Alfaya, "Use of rice straw as biosorbent for removal of Cu (II), Zn (II), Cd (II) and Hg (II) ions in industrial effluents", Journal of Hazardous Materials, 166 (1), 383-388, 2009.

I. Ghodbane and O. Hamdaoui, "Removal of mercury (II) from aqueous media using eucalyptus bark: Kinetic and equilibrium studies", Journal of Hazardous Materials, 160 (2-3), 301-309, 2008.

V. A. Anagnostopoulos, I. D. Manariotis, H. K. Karapanagioti, and C. V. Chrysikopoulos, "Removal of mercury from aqueous solutions by malt spent rootlets", Chemical engineering journal, 213, 135-141, 2012.

M. Zabihi, A. H. Asl, and A. Ahmadpour, "Studies on adsorption of mercury from aqueous solution on activated carbons prepared from walnut shell", Journal of Hazardous Materials, 174 (1-3), 251-256, 2010.

A. Demirbas, "Heavy metal adsorption onto agro-based waste materials: a review", Journal of Hazardous Materials, 157 (2-3), 220-229, 2008.

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Publicado

2019-07-19