Contribuciones fundamentales para el desarrollo tecnológico de materiales avanzados de carbono a partir de alquitrán de hulla
DOI:
https://doi.org/10.15665/rp.v10i2.227Keywords:
Alquitrán de hulla, Mesofase de brea, Carbonización, Materiales avanzados de carbono.Abstract
La brea generada a partir de alquitrán de hulla constituye un precursor de bajo coste, de materiales avanzados de
carbono de excelentes prestaciones mecánicas debido a su alto rendimiento en carbono con estructura grafítica
derivado de su alto grado de aromaticidad. En este artículo se revisan las contribuciones que han dado impulso al
desarrollo tecnológico de los materiales avanzados de carbono obtenidos a partir de alquitrán de hulla. Se analiza
el efecto de las condiciones experimentales, de cada una de las etapas de síntesis, sobre los parámetros característicos
de la materia en las diferentes fases de procesamiento que incluyen la coquización del carbón, la destilación
del alquitrán, la pirólisis de la brea y la carbonización de la mesofase.
References
Roy J. Irwin et. al., Enviromental Contaminants Encyclopedia
Coal tar Entry, Colorado State University, july 1,
M. Granada, Breas: composición y comportamiento
en pirolisis, Boletín del Grupo Español del Carbón, ISSN
-6094, No. 20 julio del 2011.
Loison R. Foch P., Boyer A., Coke, Quality and Production
CERCHAR, Cambridge, Great Britain 1989.
Hardashan S. Valia, (2007) Coke Production For Blast
Furnace Ironmaking, disponible desde:
org/en/Making%20Steel/How%20ItS%Made/Processes/
Processes%20Info/Coke%20Production%20For%20
Bast%20Furnace%20Ironmaking.aspx>, [Acceso 22 de junio
del 2012].
Rodríguez-Reinoso, F. (1989): “Comité Internacional
para la Caracterización y la Terminología del Carbón. Publicación
de 73 definiciones”. Carbon, 27, 305-312.
Alcaliz-Monge, J., Carazorla-Amoros, D., Linhares-
Solano, A., Characterization of coal tar pitches by thermal
analysis, infrared spectroscopy and solvent fractionation,
Fuel, 80, 41-48, 2001.
Montes Moran, M.A., Crespo, J.L., Young, R.J., Garcia,
R., Moinelo, S.R., Mesophase from coal tar pitch: a Raman
spectroscopy study, Fuel Procc. Tech., 78, 207-212, 2002.
Marsh H. Heintz E.A., Rdríguez-Reinoso F., editors,
Introduction to carbon technologies. Alicante, Spain: University
of Alicante Press, 1997.
Rand B., Hosty A.J., West S. In: Marsh H, editor. Introduction
to carbon science, London, Butterworths, 1989,
p.75.
Otani S. Oya A., In Bacha J.D., Newman J.W., White
J.L., editors, Petroleum-derived carbons, ACS Symposium
Series, vol. 303, Washington D.C.: American Chemical Society.
Tlomak P., Wapner P.G., Wright M.A., Extended Abstract
th Biennal Conference on Carbon, 1989, p. 323.
Cheung T., Turpin M., Rand. B., Controlled stress oscillatory
rheometry of mesophase pitches, Carbon, 34, 265-
, 1996.
Briggs, D., Viscosity of coal tar pitch at elevated temperatures,
Fuel, 59, 201-207, 1980.
Romovacek, G.R., The Determination of the Quinoline-
Insoluble (QI) content of tar and pitch, Carbon, 23 (6),
-611, 1984.
Taylor, G.H., Pennock, G.M., Fitz Gerald, J.D.,
Brunckhorst, L.F., Influence of QI on Mesophase structure,
Carbon, 31 (2), 341-354, 1993.
Krupinski, Effects of Tar Quinoline Insolubles on Manufactured
Carbon Performance, 1992, Iron Making Conference
Proceedings.
Rodriguez-Reinoso F. et al., The Role of carbon Materials
in Heterogeneous Catalysis, Carbon 1998; 36:1015.
Marsh, H., Martinez Escandell, M., Rodriguez Reinoso,
F., Semicokes from pitch pyrolysis: mechanisms and
kinetics, Carbon, 37, 363-390, 1999.
Jone S.S., Hildebrandt R. D., Anode Carbon Reactivity,
Light Metals 1974, pp 569-574.
Limonchi A., Increasing the oxidation Resistance of
Carbonaceous bodes, Light Metals 1981, pp 459-470.
Mianowski, A., Blazewicz, S., Robak, Z., Analysis of
the carbonization and formation of coal tar pitch Mesophase
under dynamic conditions, Carbon, 41, 2413-2424, 2003.
Juan M. D. Tascón, Materiales de carbón: estructura y
formas, Óptica Pura y Aplicada, 40(2), 149-159, 2007.
Shunk Kohlenstofftechnik, Tomado desde:
www.schunk.pt/PT/catalogos/ Fabricacao_e_propriedades_
de_materiais_de_grafite.pdf>, [Acceso el 22 de junio
del 2012].
Tamai, H., Marsuoka, S., Ishihara, M., Yasuda, H.,
New carbon materials from pitch containing organotin
compounds for anode of lithium ion batteries, Carbon, 39,
-1523, 2001.
Petrova, B., Tsyntsarski, B., Budinova, T., Petrov, N.,
Ania, C.O., Parra, J.B., Mladenov, M., Tzvetkov, P., Synthesis
of nanoporous carbons from mixtures of coal tar pitch
and furfural and their application as electrode materials,
Fuel Procc. Tech., 91, 1710-1716, 2010.
Y. Tanabe, E. Yasuda, “Carbon alloys”, Carbon 38, 329-
, 2000.
E. Yasuda, M. Inagaki, K. Kaneko, M. Endo, A. Oya, Y.
Tanabe, Carbon Alloys. New Concepts to Develop Carbon
Science and Technology. Elsevier, Amsterdam (2003).
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