Efecto catalítico del Na2CO3 sobre la pirólisis de los residuos del sorgo (Sorghum bicolor L. Moench)
DOI:
https://doi.org/10.15665/rp.v19i1.2160Abstract
In the present study, the catalytic effect of Na2CO3 on the pyrolysis of sorghum leaves and stalks was evaluated in the temperature range of 20 to 800 °C at three heating rates using thermogravimetric analysis coupled to Fourier transform infrared spectroscopy (TGA-FTIR). The results were adjusted with the nth-order reaction model, the isoconversional method, and the distributed activation energy model (DAEM). The latter model fits properly with three pseudo components to the first derivative thermogravimetry curves. The kinetic parameters calculated for the activation energy and pre-exponential factor are in the range of 159 to 195 kJ/mol, and 5.16E+13 to 5.13E+14 s-1, respectively. The analysis of the IR spectra allowed us to identify compounds such as, CO2, H2O, CH4, CO, HCN, C4H4O, HCOOH, and CH3COOH as the gases evolved during thermal decomposition. Moreover, the thermogravimetric curves show that the addition of sodium carbonate as a catalyst decreases the peak temperatures of the pyrolysis process of sorghum residues, and reduces the activation energy associated with the lignin and hemicellulose pyrolysis processes of the sorghum leaves and stems.
References
DNP, (2016) Pérdida y desperdicio de alimentos en Colombia [Internet], Bogotá. Disponible desde <https://mrv.dnp.gov.co/Documentos%20de%20Interes/Perdida_y_Desperdicio_de_Alimentos_en_colombia.pdf> [Acceso 22 de octubre 2019]
A. Pérez, O. Saucedo, J. Iglesias, H. Wencomo, F. Reyes, G. Oquendo, I. Milián. (2010). Caracterización y potencialidades del grano de sorgo (Sorghum bicolor L. Moench)”, Pastos y Forrajes [on line], 33 (1). Disponible desde <http://scielo.sld.cu/scielo.php?script=sci_arttext&pid=S0864-03942010000100001&lng=es&nrm=iso> [Acceso 22 de octubre 2019]
MINISTERIO DE AGRICULTURA Y DESARROLLO RURAL, (2017) Sorgo, Evaluaciones agropecuarias municipales. Disponible desde <https://www.agronet.gov.co/Documents/25-SORGO_2017.pdf> [Acceso 22 de octubre 2019]
T. Dickerson, J. Soria, “Catalytic Fast Pyrolysis: A Review”, Energies, (6), 514-538, 2013.
J. Fermoso, J.M. Coronado, D.P. Serrano, P. Pizarro, “Pyrolysis of microalgae for fuel production”. En: Microalgae-based biofuels and bioproducts, C. Gonzalez-Fernandez, R. Muñoz, Woodhead Publishing, 2017, pp. 259-281.
A. Pattiya, “Catalytic pyrolysis”. En: Direct Thermochemical Liquefaction for Energy Applications, L. Rosendahl, Woodhead Publishing, 2018, pp. 29-64.
K. Acıkalın, “Pyrolytic characteristics and kinetics of pistachio shell by thermogravimetric analysis”, Journal of Thermal Analysis and Calorimetry, 109 (1), 227-235, 2012.
A. Soria-Verdugo, N. García-Hernando, L. M. García-Gutiérrez, U. Ruiz-Rivas, “Analysis of biomass and sewage sludge devolatilization using the distributed activation energy model”, Energy Conversion and Management, 65, 239-244, 2013.
T. Ona, T. Sonoda, M. Shibata, K. Fukazawa, “Small-scale method to determine the content of wood components from multiple eucalypt samples. Tappi Journal, 78 (3), 121-126, 1995.
S. Hu, A. Jess, M. Xu, “Kinetic study of Chinese biomass slow pyrolysis: comparison of different kinetic models”, Fuel, 86 (17), 2778-2788, 2007.
A. Albis, C. Ariza, E. Ortiz, I. Piñeres, A. Santander, “Estudio TG-MS de la gasificación del carbonizado de la cáscara de Copoazú (Theobroma Glandiflorum)”, INGE CUC, 15 (1), 25-35, 2019,
B. Jankovíc, “The pyrolysis process of wood biomass samples under isothermal experimental conditions—energy density considerations: application of the distributed apparent activation energy model with a mixture of distribution functions”, Cellulose, 21, 2285-2314, 2014.
G. Várhegyi, P. Szabó, and M. J. Antal, “Kinetics of charcoal devolatilization”, Energy & Fuels, 16 (3), 274-731, 2002.
V. Vand, “A theory of the irreversible electrical resistance changes of metallic films evaporated in vacuum”, Proceedings of the Physical Society, 55 (3), 222-246, 1943.
Z. Cheng, W.Wu, P. Ji, X. Zhou, R. Liu, J. Cai, “Applicability of Fraser–Suzuki function in kinetic analysis of DAEM processes and lignocellulosic biomass pyrolysis processes, Journal of Thermal Analysis and Calorimetry, 119 (2), 1429-1438, 2014.
E. Donskoi, D. l. S. McElwain, “Optimization of coal pyrolysis modeling”, Combustion and flame, 122 (3), 359–367, 2000.
A. Carroll, C. Somerville, “Cellulosic Biofuels”, Annual review of plant biology. Stanford University, 60 (1), 165-182, 2009.
V. Dhyani, T. Bhaskar, “A comprehensive review on the pyrolysis of lignocellulosic biomass”, Renewable Energy, 129, 695-716, 2017.
A. Saffe, A. Fernández, M. Echegaray, G. Mazza, R. Rodriguez, “Pyrolysis kinetics of regional agro-industrial wastes using isoconversional methods”, Biofuels, 1-13, 2017.
W. Carvalho, T. Oliveira, C. Cardoso, C.Ataíde, “Thermogravimetric analysis and analytical pyrolysis of a variety of lignocellulosic sorghum”, Chemical Engineering Research and Design, 9, 337-345, 2014.
A. García, J. Ariza, J. Martín, J. Díaz, “Kinetic models based in biomass components for the combustion and pyrolysis of sewage sludge and its compost”, Journal of Analytical and Applied Pyrolysis, 86 (1), 108-114, 2009.
K. Acikalin, “Thermogravimetric analysis of walnut shell a pyrolysis feedstock”, J Therm Anal Calorim, 105 (1), 145-150, 2011.
J. Wang, M. Zhang, M. Chen, F. Min, S. Zhang, Z. Ren, Y. Yan, “Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass”, Thermochimica Acta, 144 (1), 110- 114, 2006.
D. Chen, J. Zhou, Q. Zhang, Qisheng. Effects of heating rate on slow pyrolysis behavior, kinetic parameters and products properties of moso bamboo. Bioresource Technology, 169, 313-319, 2014.
Y. Rueda-Ordoñez, K. Tannous, “Isoconversional kinetic study of the thermal decomposition of sugarcane straw for thermal conversion processes”, Bioresource Technology, 196, 136-144, 2015.
M. Martín-Lara, G. Blázquez, M. Zamora, M. Calero, “Kinetic modelling of torrefaction of olive tree pruning”, Applied Thermal Engineering, 113, 1410-1418, 2016.
J. Cai, L. Ji, “Pattern search method for determination of DAEM kinetic parameters from non-isothermal TGA data of biomass”, J. Math. Chem, 42 (3), 547-553, 2007.
J. Cai, W. Wu, R. Liu, “An overview of distributed activation energy model and its application in the pyrolysis of lignocellulosic biomass”, Renew. Sustain. Energy Rev, 36, 236-246, 2014.
B. Baruah, P. Tiwari, P. Thakur, R. Kataki, “TGA-FTIR analysis of upper assam oil shale, optimization of lab-scale pyrolysis process parameters using RSM”, Journal of Analytical and Applied Pyrolysis, 135, 397-405, 2018.
H. Yang, R. Yan, H. Chen, D. Ho Lee, C. Zheng, “Characteristics of hemicellulose, cellulose and lignin pyrolysis”, Fuel, 86, 1781-1788, 2007.
T. Suzuki, T. Yamada, N. Okazaki, A. Tada, M. Nakanishi, M. Futamata, H.T. Chen, “Electromagnetic shielding capacity of wood char loaded with nickel”, Materials Science Research International, 7 (3), 206-212, 2001.
D. Guo, S. Wua, B. Liu, X. Yin, Q. Yang, “Catalytic effects of NaOH and Na2CO3 additives on alkali lignin pyrolysis
and gasification”, Applied Energy ,95, 22-30, 2012.
Downloads
Published
Issue
Section
License
Copyright (c) 2021 Alberto Ricardo Albis Arrieta, Mariusy Colón Castro, Mary Quintero Parra
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
The authors to publish in this journal agree to the following conditions:
- The authors transfer the copyright and give the the journal first publication right of the work registered with Creative Commons Attribution License, which allows third parties to use the published work on the condition of always mentioning the authorship and first publication in this journal.
- The authors may perform other independent and additional contractual arrangements for the non-exclusive distribution of the version of the article published in this issue (E.g., Inclusion in an institutional repository or publication in a book), it must be indicated clearly that the work was first published in this journal.
- It allows and encourages the authors to publish their work online (eg institutional or personal pages) before and during the review and publication process. It can lead to productive exchanges and greater and faster dissemination of the published work (see The Effect of Open Access)
Instructions to fill out Certificate of Originality and Copyright Assignment
- Click here and get the forms of Certificate of Originality and Copyright Assignment .
- In each field to fill out, click and complete the corresponding information.
- Once the fields are filled out, at the end of the form copy your scanned signature or digital signature. Please adjust the size of the signature on the form.
- Finally, you can save them as pdf files and send them through the OJS platform as an attachment.
