Remoción de Mercurio (II) en solución acuosa usando residuo industrial de yuca (Manihot esculenta)
DOI:
https://doi.org/10.15665/rp.v17i2.1951Keywords:
Adsorción, Hg (II), Metales pesados, Residuo Industrial, YucaAbstract
Se estudió la remoción de mercurio (II) en solución acuosa usando residuo industrial de yuca teniendo en cuenta variables como el pH y la concentración inicial del metal. El material adsorbente fue pretratado y caracterizado. Se determinó que la cinética de adsorción se ajusta a un modelo de primer orden y que el tiempo para el equilibrio de remoción es de dos horas. La capacidad máxima de remoción que se obtuvo fue de 0.03 mmol/g a una concentración inicial de mercurio (II) de 400 mg/L y a un pH de 6. Adicionalmente, se obtuvo que la adsorción de este metal a pH de 4.75 y 6 se ajusta de manera adecuada al modelo de adsorción de Langmuir.
References
A. Abdolali, W. Guo, H. H. Ngo, S.-S. Chen, N. C. Nguyen, and K. L. Tung, "Typical lignocellulosic wastes and by-products for biosorption process in water and wastewater treatment: a critical review", Bioresource technology, 160, 57-66, 2014.
E. Khoramzadeh, B. Nasernejad, and R. Halladj, "Mercury biosorption from aqueous solutions by sugarcane bagasse", Journal of the Taiwan Institute of Chemical Engineers, 44 (2), 266-269, 2013.
S. Basha, Z. Murthy, and B. Jha, "Sorption of Hg (II) onto Carica papaya: experimental studies and design of batch sorber", Chemical engineering journal, 147 (2-3), 226-234, 2009.
A. Esmaeili, B. Saremnia, and M. Kalantari, "Removal of mercury (II) from aqueous solutions by biosorption on the biomass of Sargassum glaucescens and Gracilaria corticata", Arabian Journal of Chemistry, 8 (4), 506-511, 2015.
S. Ricordel, S. Taha, I. Cisse, and G. Dorange, "Heavy metals removal by adsorption onto peanut husks carbon: characterization, kinetic study and modeling", Separation and purification technology, 24 (3), 389-401, 2001.
E. El-Shafey, "Removal of Zn (II) and Hg (II) from aqueous solution on a carbonaceous sorbent chemically prepared from rice husk", Journal of Hazardous Materials, 175 (1-3), 319-327, 2010.
N. Asasian, T. Kaghazchi, and M. Soleimani, "Elimination of mercury by adsorption onto activated carbon prepared from the biomass material", Journal of Industrial and Engineering Chemistry, 18 (1), 283-289, 2012.
S. H. Lee, C. H. Jung, H. Chung, M. Y. Lee, and J.-W. Yang, "Removal of heavy metals from aqueous solution by apple residues", Process Biochemistry, 33 (2), 205-211, 1998.
S.-A. Sajjadi, A. Mohammadzadeh, H. N. Tran, I. Anastopoulos, G. L. Dotto, Z. R. Lopičić, S. Sivamani, A. Rahmani-Sani, A. Ivanets, and A. Hosseini-Bandegharaei, "Efficient mercury removal from wastewater by pistachio wood wastes-derived activated carbon prepared by chemical activation using a novel activating agent", Journal of Environmental Management, 223, 1001-1009, 2018.
Z. Liu, W. Yang, W. Xu, and Y. Liu, "Removal of elemental mercury by bio-chars derived from seaweed impregnated with potassium iodine", Chemical engineering journal, 339, 468-478, 2018.
C. T. Tovar, E. R. Paternina, J. G. Mercado, and J. M. Bohorquez, "Evaluación de la biosorción con bagazo de palma africana para la eliminación de Pb (II) en solución", Prospectiva, 13 (1), 59-67, 2015.
R. Howeler, N. Lutaladio, and G. Thomas, "Save and grow: cassava, food and agriculture", Rome: Organization of the United Nations,2013.
M. P. Cereda and M. Takahashi, "Cassava wastes: their characterization and uses and treatment in Brazil", Cassava flour and starch: Progress in research and development, (271), 221-232, 1996.
A. Bhatnagar, M. Sillanpää, and A. Witek-Krowiak, "Agricultural waste peels as versatile biomass for water purification–a review", Chemical engineering journal, 270, 244-271, 2015.
M. Horsfall Jr and A. Abia, "Sorption of cadmium (II) and zinc (II) ions from aqueous solutions by cassava waste biomass (Manihot sculenta Cranz)", Water research, 37 (20), 4913-4923, 2003.
M. Pájaro and O. Romero, (2012) "Remoción de cromo (VI) en un medio acuoso mediante el uso de la cáscara de la yuca (Manihot esculenta)." Tesis de pregrado, Facultad de Ingeniería, Universidad del Atlántico, Barranquilla.
ICONTEC, "Productos Químicos Industriales. Carbón Activado. Métodos de Ensayo," vol. NTC 4467, ed. Bogotá: ICONTEC, 1998, p. 30.
M. Carrier, A. Loppinet-Serani, D. Denux, J.-M. Lasnier, F. Ham-Pichavant, F. Cansell, and C. Aymonier, "Thermogravimetric analysis as a new method to determine the lignocellulosic composition of biomass", Biomass and Bioenergy, 35 (1), 298-307, 2011.
I. De La Calle, N. Cabaleiro, V. Romero, I. Lavilla, and C. Bendicho, "Sample pretreatment strategies for total reflection X-ray fluorescence analysis: A tutorial review", Spectrochimica Acta Part B: Atomic Spectroscopy, 90, 23-54, 2013.
G. M. Gadd, "Biosorption: critical review of scientific rationale, environmental importance and significance for pollution treatment", Journal of Chemical Technology & Biotechnology: International Research in Process, Environmental & Clean Technology, 84 (1), 13-28, 2009.
O. Corredor Becerra, (2008) "Evaluación del potencial energético de la biomasa residual proveniente de cultivos energéticos." Ingeniero Químico, Universidad Industrial de Santander.
A. N. Kosasih, J. Febrianto, J. Sunarso, Y.-H. Ju, N. Indraswati, and S. Ismadji, "Sequestering of Cu (II) from aqueous solution using cassava peel (Manihot esculenta)", Journal of Hazardous Materials, 180 (1-3), 366-374, 2010.
P. Prinsen, "Composición química de diversos materiales lignocelulósicos de interés industrial y análisis estructural de sus ligninas",2010.
C. G. Rocha, D. A. M. Zaia, R. V. da Silva Alfaya, and A. A. da Silva Alfaya, "Use of rice straw as biosorbent for removal of Cu (II), Zn (II), Cd (II) and Hg (II) ions in industrial effluents", Journal of Hazardous Materials, 166 (1), 383-388, 2009.
I. Ghodbane and O. Hamdaoui, "Removal of mercury (II) from aqueous media using eucalyptus bark: Kinetic and equilibrium studies", Journal of Hazardous Materials, 160 (2-3), 301-309, 2008.
V. A. Anagnostopoulos, I. D. Manariotis, H. K. Karapanagioti, and C. V. Chrysikopoulos, "Removal of mercury from aqueous solutions by malt spent rootlets", Chemical engineering journal, 213, 135-141, 2012.
M. Zabihi, A. H. Asl, and A. Ahmadpour, "Studies on adsorption of mercury from aqueous solution on activated carbons prepared from walnut shell", Journal of Hazardous Materials, 174 (1-3), 251-256, 2010.
A. Demirbas, "Heavy metal adsorption onto agro-based waste materials: a review", Journal of Hazardous Materials, 157 (2-3), 220-229, 2008.
Downloads
Published
Issue
Section
License
The authors to publish in this journal agree to the following conditions:
- The authors transfer the copyright and give the the journal first publication right of the work registered with Creative Commons Attribution License, which allows third parties to use the published work on the condition of always mentioning the authorship and first publication in this journal.
- The authors may perform other independent and additional contractual arrangements for the non-exclusive distribution of the version of the article published in this issue (E.g., Inclusion in an institutional repository or publication in a book), it must be indicated clearly that the work was first published in this journal.
- It allows and encourages the authors to publish their work online (eg institutional or personal pages) before and during the review and publication process. It can lead to productive exchanges and greater and faster dissemination of the published work (see The Effect of Open Access)
Instructions to fill out Certificate of Originality and Copyright Assignment
- Click here and get the forms of Certificate of Originality and Copyright Assignment .
- In each field to fill out, click and complete the corresponding information.
- Once the fields are filled out, at the end of the form copy your scanned signature or digital signature. Please adjust the size of the signature on the form.
- Finally, you can save them as pdf files and send them through the OJS platform as an attachment.
