Interacción de derivados de Fenilhidrazona con aniones: efecto de los sustituyentes en el grupo fenilo

Authors

  • Glenys Ramírez-Valbuena La Universidad del Zulia
  • Marielis Chirinos-Iguarán Instituto Venezolano de Investigaciones Científicas image/svg+xml
  • Katerin Boscán-Meleán Instituto Venezolano de Investigaciones Científicas image/svg+xml
  • Rodolfo Izquierdo La Universidad del Zulia
  • Mayamaru Guerra La Universidad del Zulia
  • Jelen Restrepo Instituto Venezolano de Investigaciones Científicas image/svg+xml

DOI:

https://doi.org/10.15665/rp.v17i1.1670

Keywords:

fenilhidrazona, sensor colorimétrico, Job Plot, complejo receptor, huésped

Abstract

Se estudió la interacción de 16 derivados fenilhidrazonas con los aniones AcO-, H2PO4-, F- y Cl- mediante espectroscopía UV-Visible. Se sintetizaron los derivados 2-fenilhidracina sin nitro, 2-nitro, 4 nitro y 2,4-dinitro de 4-hidroxi (1-4), 4-metoxi (5-8), 4-dimetilamino bencilideno (9-12) y piridina (13-16). Se evaluó la relación entre la estructura de las hidrazonas y la constante de asociación. La estequiometría de los complejos se determinó por el método de variaciones continuas y la constante de asociación se determinó por el método de ajuste no lineal. Los derivados 4, 8, 12 y 15 presentaron interacción con AcO-;  esto se evidencia por el corrimiento batocrómico de la banda de absorción de la hidrazona. Sin embargo, los derivados 12 y 15 no se ajustaron a las ecuaciones aplicadas en este trabajo.  Los resultados para los derivados 4 y 8 sugieren la formación de un complejo del tipo receptor:huesped con estequiometria 1:2 y constantes de [K1 = 1,758 (±0,026)×104 and K2 = 2,310 (±0,033)×104] mol-1∙dm3 and [K1 = 4,703 (±0,073)×104 and K2 = 2,000 (0,066)×104] mol-1∙dm3 respectivamente.

Author Biographies

  • Glenys Ramírez-Valbuena, La Universidad del Zulia

    Química

    Laboratorio de Electrónica Molecular

  • Marielis Chirinos-Iguarán, Instituto Venezolano de Investigaciones Científicas

    Química

    Laboratorio de Investigación en Síntesis Sustentable de Nuevos Materiales

  • Katerin Boscán-Meleán, Instituto Venezolano de Investigaciones Científicas

    Química

    Laboratorio de Investigación en Síntesis Sustentable de Nuevos Materiales

  • Rodolfo Izquierdo, La Universidad del Zulia

    M. Sc. en Química

    Laboratorio de Química Teórica y Computacional

  • Mayamaru Guerra, La Universidad del Zulia

    Dra. en Física

    Laboratorio de Polímeros

  • Jelen Restrepo, Instituto Venezolano de Investigaciones Científicas

    Dra. en Química

    Laboratorio de Investigación en Síntesis Sustentable de Nuevos Materiales

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Published

2019-04-04

Issue

Vol. 17 No. 1 (2019): Enero-Junio

Section

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