Microstructural characterization of titanium alloy Ti6Al4V thermally oxidized/Caracterización microestructural de la aleación de titanio Ti6Al4V oxidada térmicamente
DOI:
https://doi.org/10.15665/rp.v16i2.1617Keywords:
Oxidación térmica, Ti6Al4V, DRX, Rutilo, AnatasaAbstract
El objetivo de este artículo es analizar el efecto de la oxidación térmica en el cambio microestructural de propiedades mecánicas de la aleación Ti6Al4V. Las muestras de titanio fueron sometidas a tratamiento de oxidación térmica entre 450°C y 850°C por espacio de 2 horas y enfriamiento lento. La morfología superficial fue analizada mediante Microscopía óptica, Microscopía electrónica de barrido, Difracción de rayos X y Análisis de dureza. Con la oxidación térmica se generó una película de óxido tipo TiO2, la cual incrementó su espesor con la temperatura, de igual forma con este aumento de temperatura la dureza del material aumentó en un 40% a 850°C con respecto al material sin tratamiento. Los resultados además mostraron que a partir de 800°C ya se muestra en su totalidad estructuras de rutilo en la superficie de las muestras.References
D. Xiong, Y. Yang, and Y. Deng, “Bio-tribological properties of UHMWPE against surface modified titanium alloy,” Surf. Coatings Technol., pp. 4–7, May 2012.
C. Leyens and M. Peters, Titanium an Titanium Alloys. Weinheim: Wiley-VCH, 2003.
F. Gil and J. P. Estany, “Aplicaciones biomédicas del titanio v sus aleaciones,” 9 p., no. c, 1993.
J. D. Park, J. B. Bronzino, Biomaterials , Principles and Applications. CRC Press, Boca Raton, FL, 2000. 2000.
G. Lütjering and J. Williams, Titanium, Second edi. New York, 2007.
X. Liu, P. Chu, and C. Ding, “Surface modification of titanium, titanium alloys, and related materials for biomedical applications,” Mater. Sci. Eng. R Reports, vol. 47, no. 3–4, pp. 49–121, Dec. 2004.
M. Jamesh, T. S. N. Sankara Narayanan, and P. K. Chu, “Thermal oxidation of titanium: Evaluation of corrosion resistance as a function of cooling rate,” Mater. Chem. Phys., vol. 138, no. 2–3, pp. 565–572, Mar. 2013.
L. C. Chuang, C. H. Luo, and S. Yang, “The structure and mechanical properties of thick rutile–TiO2 films using different coating treatments,” Appl. Surf. Sci., vol. 258, no. 1, pp. 297–303, Oct. 2011.
D. Sivaramakrishna, Y. Brama and Y. Sun, “Thick rutile layer on titanium for tribological applications,” Tribol. Int., vol. 40, no. 2, pp. 329–334, Feb. 2007.
M. Duraiselvam, A. Valarmathi, S. M. Shariff, and G. Padmanabham, “Laser surface nitrided Ti-6Al-4V for light weight automobile disk brake rotor application,” Wear, vol. 309, no. 1–2, pp. 269–274, Jan. 2014.
M. V. Diamanti and M. P. Pedeferri, “Effect of anodic oxidation parameters on the titanium oxides formation,” Corros. Sci., vol. 49, no. 2, pp. 939–948, Feb. 2007.
A. R. Ebrahimi, F. Zarei, and R. A. Khosroshahi, “Effect of thermal oxidation process on fatigue behavior of Ti-4Al-2V alloy,” Surf. Coatings Technol., vol. 203, no. 3–4, pp. 199–203, Nov. 2008.
S. Kumar, T. S. N. Sankara Narayanan, S. Ganesh Sundara Raman, and S. K. Seshadri, “Thermal oxidation of Ti6Al4V alloy: Microstructural and electrochemical characterization,” Mater. Chem. Phys., vol. 119, no. 1–2, pp. 337–346, Jan. 2010.
A. Bloyce, P. Y. Qi, H. Dong, and T. Bell, “Surface modification of titanium alloys for combined improvements in corrosion and wear resistance,” Surf. Coatings Technol., vol. 107, no. 2–3, pp. 125–132, 1998.
H. Güleryüz and H. Cimenoglu, “Effect of thermal oxidation on corrosion and corrosion – wear behaviour of a Ti – 6Al – 4V alloy,” Biomaterials, vol. 25, pp. 3325–3333, 2004.
S. Kumar, T. S. N. S. Narayanan, S. Ganesh Sundara Raman, and S. K. Seshadri, “Surface modification of CP-Ti to improve the fretting-corrosion resistance: Thermal oxidation vs. anodizing,” Mater. Sci. Eng. C, vol. 30, no. 6, pp. 921–927, Jul. 2010.
J. A. Fernandes, E. C. Kohlrausch, S. Khan, and R. C. Brito, “Effect of anodisation time and thermal treatment temperature on the structural and photoelectrochemical properties of TiO2 nanotubes,” J. Solid State Chem., vol. 251, no. February, pp. 217–223, 2017.
ASTM Norma, “F-136-Standard Specification for Wrought Titanium-6Aluminum-4Vanadium ELI ( Extra Low Interstitial ) Alloy for Surgical Implant Applications (UNS R56401).,” ASTM Copyright., pp. 6–10, 2012.
S. Kumar, T. S. N. S. Narayanan, S. G. S. Raman, and S. K. Seshadri, “Thermal oxidation of CP-Ti: Evaluation of characteristics and corrosion resistance as a function of treatment time,” Mater. Sci. Eng. C, vol. 29, no. 6, pp. 1942–1949, Aug. 2009.
U. Diebold, “The surface science of titanium dioxide,” Surf. Sci. Rep., vol. 48, no. 5–8, pp. 53–229, Jan. 2003.
Downloads
Additional Files
Published
Issue
Section
License
The authors to publish in this journal agree to the following conditions:
- The authors transfer the copyright and give the the journal first publication right of the work registered with Creative Commons Attribution License, which allows third parties to use the published work on the condition of always mentioning the authorship and first publication in this journal.
- The authors may perform other independent and additional contractual arrangements for the non-exclusive distribution of the version of the article published in this issue (E.g., Inclusion in an institutional repository or publication in a book), it must be indicated clearly that the work was first published in this journal.
- It allows and encourages the authors to publish their work online (eg institutional or personal pages) before and during the review and publication process. It can lead to productive exchanges and greater and faster dissemination of the published work (see The Effect of Open Access)
Instructions to fill out Certificate of Originality and Copyright Assignment
- Click here and get the forms of Certificate of Originality and Copyright Assignment .
- In each field to fill out, click and complete the corresponding information.
- Once the fields are filled out, at the end of the form copy your scanned signature or digital signature. Please adjust the size of the signature on the form.
- Finally, you can save them as pdf files and send them through the OJS platform as an attachment.
